Estudio de la degradación de fenol sobre catalizador de arcilla pilarizada-Study of the degradation of phenol on pillar clay catalyst

  • Julio Andrés Cardona-Castaño Universidad de Caldas
  • Gonzalo Taborda-Ocampo Universidad de Caldas

Resumen

Se investiga la oxidación de fenol sobre catalizador de arcilla pilarizada en un reactor operando tanto en batch como en semibatch. Los experimentos fueron llevados a cabo a temperatura ambiente y presión atmosférica, con concentración de fenol de 100 mg/L, concentración de catalizador de 0,5 y 2,75 g/L y concentración de peróxido de hidrógeno del  50 y el 100 % de la cantidad estequiométrica necesaria para la total degradación de fenol. Se comparan ambos procesos en términos de degradación de fenol, degradación de H2O2, formación y degradación de intermediarios aromáticos y ácidos de cadena corta. Se determinó, que la velocidad de degradación de fenol e intermediarios aromáticos es más lenta en el proceso en semibatch. Sin embargo, hay un uso más eficiente del peróxido de hidrógeno en el proceso semibatch, favoreciendo la reacción con las especies orgánicas y  reduciendo las reacciones competitivas.

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Biografía del autor/a

Julio Andrés Cardona-Castaño, Universidad de Caldas
Docente Universidad de caldas. Departamento de Química
Gonzalo Taborda-Ocampo, Universidad de Caldas
Docente Universidad de Caldas

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Cómo citar
Cardona-Castaño, J., & Taborda-Ocampo, G. (2016). Estudio de la degradación de fenol sobre catalizador de arcilla pilarizada-Study of the degradation of phenol on pillar clay catalyst. Revista Científica, 2(25), 265-279. https://doi.org/10.14483//udistrital.jour.RC.2016.25.a10
Publicado: 2016-08-31
Sección
Ciencia e ingeniería