DOI:
https://doi.org/10.14483/23448350.19427Publicado:
2023-01-02Número:
Vol. 46 Núm. 1 (2023): Enero-Abril 2023Sección:
Ciencias Básicas y EducaciónDesarrollo de un método analítico por cromatografía iónica para la cuantificación de aniones en aguas residuales de origen minero
Development of an Analytical Method by Ion Chromatography for the Quantification of Anions in Wastewater of Mining Origin
Palabras clave:
aguas residuales, cromatografía iónica, minería, sensibilidad, tiocianato, validación (es).Palabras clave:
ion chromatography, mining, sensitivity, thiocyanate, validation, wastewater (en).Descargas
Resumen (es)
El objetivo de este trabajo fue desarrollar un método por cromatografía iónica con detector de conductividad para la determinación simultánea de tiocianato en aguas residuales mineras y aniones como bromuro, cloruro, fluoruro, fosfato, nitrito, nitrato y sulfato. Como eluente se utilizó hidróxido de potasio (KOH) en un rango de concentraciones entre , flujos entre y corriente del supresor entre . Se determinó que la mejor separación de las especies estudiadas se logró con una concentración de KOH de en modo isocrático y un flujo de en una columna analítica AS20. Además, se determinó una serie de parámetros analíticos como sensibilidad, linealidad, precisión, exactitud y límites de detección y cuantificación que permiten la validación del método analítico. Se obtuvieron valores de desviación estándar relativa (RSD) menores al 20 % en cuanto a la precisión del método analítico, con recuperaciones mayores al 96 %. El método desarrollado es por lo tanto adecuado para la determinación de tiocianato y aniones en aguas residuales de origen minero.
Resumen (en)
The objective of this work was to develop a method by ion chromatography with conductivity detector for the simultaneous determination of thiocyanate in mining wastewater and anions such as bromide, chloride, fluoride, phosphate, nitrite, nitrate and sulfate. Potassium hydroxide (KOH) was used as an eluent in a range of concentrations between , flows between and suppressor current between . It was determined that the best separation of the species was achieved with a KOH concentration of in isocratic mode and a flow of in an AS20 analytical column. In addition, a series of analytical parameters such as sensitivity, linearity, precision, accuracy and limits of detection and quantification were determined that allow the validation of the analytical method. Relative standard deviation (RSD) values of less than 20 % were obtained in terms of the accuracy of the analytical method, with recoveries greater than 96 %. The method developed is therefore suitable for the determination of thiocyanate and anions in wastewater of mining origin.
Referencias
Aguiar, J. B., Martins, A. M., Almeida, C., Ribeiro, H. M., Marto, J. (2022). Water sustainability: A waterless life cycle for cosmetic products. Sustainable Production and Consumption, 32, 35-51. https://doi.org/10.1016/j.spc.2022.04.008
Alvillo-Rivera, A., Garrido-Hoyos, S., Buitrón, G., Thangarasu-Sarasvathi, P., Rosano-Ortega, G. (2021). Biological treatment for the degradation of cyanide: A review. Journal of Materials Research and Technology, 12, 1418-1433. https://doi.org/10.1016/j.jmrt.2021.03.030
Amin, M., Lim, L. W., Takeuchi, T. (2008). Determination of common inorganic anions and cations by non-suppressed ion chromatography with column switching. Journal of Chromatography A, 1182(2), 169-175. https://doi.org/10.1016/j.chroma.2008.01.007
APHA. (1998). Standard Methods for the Examination of Water and Wastewater. Washington DC: American Public Health Association
Budaev, S. L., Batoeva, A. A., Tsybikova, B. A. (2015). Degradation of thiocyanate in aqueous solution by persulfate activated ferric ion. Minerals Engineering, 81, 88-95. https://doi.org/10.1016/j.mineng.2015.07.010
Cacace, D., Ashbaugh, H., Kouri, N., Bledsoe, S., Lancaster, S., Chalk, S. (2007). Spectrophotometric determination of aqueous cyanide using a revised phenolphthalin method. Analytica Chimica Acta, 589(1), 137-141. https://doi.org/10.1016/j.aca.2007.02.004
Causse, J., Thomas, O., Jung, A. V., Thomas, M. F. (2017). Direct DOC and nitrate determination in water using dual pathlength and second derivative UV spectrophotometry. Water Research, 108, 312-319. https://doi.org/10.1016/j.watres.2016.11.010
Chen, G., Ye, Y., Yao, N., Hu, N., Zhang, J., Huang, Y. (2021). A critical review of prevention, treatment, reuse, and resource recovery from acid mine drainage. Journal of Cleaner Production, 329, e129666. https://doi.org/10.1016/j.jclepro.2021.129666
Da Silva, M., Fernandes Sako, A. V., Micke, G. A., Vitali, L. (2020). A rapid method for simultaneous determination of nitrate, nitrite and thiocyanate in milk by CZE-UV using quaternary ammonium chitosan as electroosmotic flow inverter. Journal of Food Composition and Analysis, 88, e103455. https://doi.org/10.1016/j.jfca.2020.103455
Destanoğlu, O., Gümüş Yılmaz, G. (2016). Determination of cyanide, thiocyanate, cyanate, hexavalent chromium, and metal cyanide complexes in various mixtures by ion chromatography with conductivity detection. Journal of Liquid Chromatography & Related Technologies, 39(9), 465-474. https://doi.org/10.1080/10826076.2016.1192044
Destanoğlu, O., Gümüş Yılmaz, G., Apak, R. (2015). Selective determination of free cyanide in environmental water matrices by ion chromatography with suppressed conductivity detection. Journal of Liquid Chromatography & Related Technologies, 38(16), 1537-1545. https://doi.org/10.1080/10826076.2015.1076460
Environment Protection Agency. (2018). Protocol for Review and Validation of New Methods for Regulated Organic and Inorganic Analytes in Wastewater Under EPA’s Alternate Test Procedure Program. Washington, DC: Office of Water, Environmental Protection Agency
Fa, Y., Yu, Y., Li, F., Du, F., Liang, X., Liu, H. (2018). Simultaneous detection of anions and cations in mineral water by two dimensional ion chromatography. Journal of Chromatography A, 1554, 123-127. https://doi.org/10.1016/j.chroma.2018.04.017
Gómez-Ordóñez, E., Alonso, E., Rupérez, P. (2010). A simple ion chromatography method for inorganic anion analysis in edible seaweeds. Talanta, 82(4), 1313-1317. https://doi.org/10.1016/j.talanta.2010.06.062
Gould, W. D., King, M., Mohapatra, B. R., Cameron, R. A., Kapoor, A., Koren, D. W. (2012). A critical review on destruction of thiocyanate in mining effluents. Minerals Engineering, 34, 38-47. https://doi.org/10.1016/j.mineng.2012.04.009
He, X., Mei, Y., Wang, Y., Sun, W., Shen, M. (2019). Determination of inorganic anions in the whole blood by ion chromatography. Journal of Pharmaceutical and Biomedical Analysis, 163, 58-63. https://doi.org/10.1016/j.jpba.2018.09.030
Ighalo, J. O., Kurniawan, S. B., Iwuozor, K. O., Aniagor, C. O., Ajala, O. J., Oba, S. N., Iwuchukwu, F. U., Ahmadi, S., Igwegbe, C. A. (2022). A review of treatment technologies for the mitigation of the toxic environmental effects of acid mine drainage (AMD). Process Safety and Environmental Protection, 157, 37-58. https://doi.org/10.1016/j.psep.2021.11.008
International Organization for Standardization. (2017). ISO/IEC 17025 - General requirements for the competence of testing and calibration laboratories
Kapinus, E. N., Revelsky, I. A., Ulogov, V. O., Lyalikov, Y. A. (2004). Simultaneous determination of fluoride, chloride, nitrite, bromide, nitrate, phosphate and sulfate in aqueous solutions at 10-9 to 10-8 % level by ion chromatography. Journal of Chromatography B, 800(1-2), 321-323. https://doi.org/10.1016/j.jchromb.2003.09.065
Langasco, I., Barracu, F., Deroma, M. A., Lopez-Sanchez, J. F., Mara, A., Meloni, P., Pilo, M. I., Estrugo, A. S., Sanna, G., Spano, N., Spanu, A. (2022). Assessment and validation of ICP-MS and IC-ICP-MS methods for the determination of total, extracted and speciated arsenic. Application to samples from a soil-rice system at varying the irrigation method. Journal of Environmental Management, 302(Pt B), e114105. https://doi.org/10.1016/j.jenvman.2021.114105
Lim, H. S., Lee, S. J., Choi, E., Lee, S. B., Nam, H. S., Lee, J. K. (2022). Development and validation of an ionic chromatography method for nitrite determination in processed foods and estimation of daily nitrite intake in Korea. Food Chemistry, 382, e132280. https://doi.org/10.1016/j.foodchem.2022.132280
Luque-Almagro, V. M., Moreno-Vivian, C., Roldán, M. D. (2016). Biodegradation of cyanide wastes from mining and jewellery industries. Current Opinion in Biotechnology, 38, 9-13. https://doi.org/10.1016/j.copbio.2015.12.004
Mahmud, M. A. P., Ejeian, F., Azadi, S., Myers, M., Pejcic, B., Abbassi, R., Razmjou, A., Asadnia, M. (2020). Recent progress in sensing nitrate, nitrite, phosphate, and ammonium in aquatic environment. Chemosphere, 259, e127492. https://doi.org/10.1016/j.chemosphere.2020.127492
Miskaki, P., Lytras, E., Kousouris, L., Tzoumerkas, P. (2007). Data quality in water analysis: Validation of ion chromatographic method for the determination of routine ions in potable water. Desalination, 213(1-3), 182-188. https://doi.org/10.1016/j.desal.2006.05.063
Talebi, S. M., Abedi, M. (2005). Determination of atmospheric concentrations of inorganic anions by ion chromatography following ultrasonic extraction. Journal of Chromatography A, 1094(1-2), 118-121. https://doi.org/10.1016/j.chroma.2005.07.118
Thangiah, A. S. (2019). Spectrophotometric determination of sulphate and nitrate in drinking water at Asia-Pacific International University Campus, Muak Lek, Thailand. Rasayan Journal of Chemistry, 12(03), 1503-1508
Uzhel, A. S., Zatirakha, A. V., Smolenkov, A. D., Shpigun, O. A. (2018). Quantification of inorganic anions and organic acids in apple and orange juices using novel covalently-bonded hyperbranched anion exchanger with improved selectivity. Journal of Chromatography A, 1567, 130-135. https://doi.org/10.1016/j.chroma.2018.06.065
Ye, M., Nesterenko, P. N., Yan, Z., Xie, P., Chen, M. (2019). Determination of inorganic anions in weak acids by using ion exclusion chromatography - Capillary ion chromatography switching column technique. Journal of Chromatography A, 1588, 169-173. https://doi.org/10.1016/j.chroma.2019.01.007
Zhou, M., Li, X., Zhang, M., Liu, B., Zhang, Y., Gao, Y., Ullah, H., Peng, L., He, A., Yu, H. (2020). Water quality in a worldwide coal mining city: A scenario in water chemistry and health risks exploration. Journal of Geochemical Exploration, 213, e106513. https://doi.org/10.1016/j.gexplo.2020.106513
Cómo citar
APA
ACM
ACS
ABNT
Chicago
Harvard
IEEE
MLA
Turabian
Vancouver
Descargar cita
Licencia
Derechos de autor 2023 Julio-Andrés Cardona-Castaño, Juan-David Rivera-Giraldo, Fernando-Antonio Chávez-Vallejo
Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-CompartirIgual 4.0.
El (los) autor(es) al enviar su artículo a la Revista Científica certifica que su manuscrito no ha sido, ni será presentado ni publicado en ninguna otra revista científica.
Dentro de las políticas editoriales establecidas para la Revista Científica en ninguna etapa del proceso editorial se establecen costos, el envío de artículos, la edición, publicación y posterior descarga de los contenidos es de manera gratuita dado que la revista es una publicación académica sin ánimo de lucro.
Institución de Educación Superior sujeta a inspección y vigilancia por el Ministerio de Educación Nacional
Acuerdo de creación N° 10 de 1948 del Concejo de Bogotá Acreditación Institucional de Alta Calidad - Resolución N° 23096 del 15 de diciembre del 2016
